Obviously if you have no fuel whatsoever, you can't ignite anything.
Lean causes detonation and preignition because the cylinder walls start to glow from the flame front hitting it. There is no way to stop the flame front from hitting the walls without that undissolved fuel.
Leftover carbon embers can cause preigniton and detonation in the next ignition stroke because they glow for a bit. They are usually caused by VERY rich mixtures or just downright shitty fuel.
I'm starting to think you are referring to how diesel engines like there mixtures. They like to run lean but as soon as they run rich and roll coal, you're starting to ruin your engine.
Now on almost any modern car engine, at light throttle, they run a stoicheometric AFR. This is to keep emissions low. 14.7:1 doesn't provide that fuel insulation layer, but at light throttle, that combustion isn't hot enough to do much to the bare walls of the chamber. Near full throttle though, the AFR goes to 13:1-ish to provide the fuel insulation layer. At this point, the bare chamber couldn't stand up to the heat, so the insulation is needed. A 13:1 ratio isn't as good with emissions or fuel economy as 14.7:1, but screw the environment, we want power!
Read the third paragraph:
https://en.wikipedia.org/wiki/Air%E2%80%93fuel_ratio
I don't know how else to explain this. I don't want to sound like a jerk, but I also believed exactly what you are saying until I blew up my 4-stroke weed wacker trying to run it lean. After that, I did some research, bought another weed wacker, and ran it a bit rich. That chamber still looks new after 5 years while the lean one died after 1 year.